Photoactivation of metal-halogen bonds in a Ni(II) NHC complex.
نویسندگان
چکیده
Photolysis of [Ni(II)(μ-Cl)Cl(IPr)](2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) activates the Ni-Cl bonds to furnish [Ni(I)(μ-Cl)(IPr)](2). Consistent with this photochemistry, a TD-DFT calculation for square planar Ni(ii) centre reveals that light excitation leads to the population of orbitals with σ*(Ni-Cl) character.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 7 شماره
صفحات -
تاریخ انتشار 2013